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Organometallics 2004 vol 23 21 p4970
Synthesis and characterization of osmium polyhydrides. X-ray crystal structures of (C 5 Me 5)OsH 5 and (C 5 Me 5) 2 Os 2 H 4. / Gross, Christopher L.; Girolami, Gregory S. In: Organometallics, Vol. 26, No. 1, 01.01.2007, p. 160-166. Research output: Contribution to journal › ArticleThe organometallic vapour deposition of aluminium oxide films in a cold wall reactor was studied at temperatures between 773 and 1273 K and the pressure range of 55–1000 hPa.Organometallic fluorides can serve as a source of organofluorine compounds. Organofluorine chemistry impacts many areas of everyday life and technology. The C-F bond is present in several pharmaceuticals, agrichemicals, fluoropolymers, refrigerants, surfactants, anesthetics, oil-repellents, catalysts, and water-repellents.
Professor Diaconescu received her B Organometallics 2004 vol 23 21 p4970.S. in 1998 from the University of Bucharest, Romania. She received her Ph.D. in 2003 from the Massachusetts Institute of Technology in Cambridge, MA. She was a postdoctoral fellow, 2003-2005, California Institute of Technology, Pasadena, CA. Paula Diaconescu joined the UCLA Chemistry & Biochemistry department.Article Organometallics, Vol. 29, No. 9, 2010 2177 Table 1. 1H NMR Dataa proton mult THF-d 8 CD 2Cl 2 CDCl 3 toluene-d 8 C 6D 6 C 6D 5Cl (CD 3) 2CO (CD 3) 2SO CD 3CN TFE-d 3 CD 3OD D 2O solvent residual"Structural and Spectroscopic Evidence for Intramolecular Agostic M···H-C and Dative Zr<-F-C(ortho) Interactions in the Zwitterionic Group 4 Metal Betaine Complexes, [(C 5 H 4)SiMe 2 (N-t-Bu)]M(+)(h-C 4 H 6)(B(C 6 F 5) 3, M = Ti, Zr", F. Hannig, R. Fröhlich, K. Bergander, G. Erker, J. L. Petersen, Organometallics 2004, 23, 4495-4502.
A New Scorpionate Ligand: Tris(4,4-dimethyl-2-oxazolinyl)borate and Its Zirconium(IV) Complexes Abstract The first example of a new class of oxazoline-based scorpionate ligand, tris(4,4-dimethyl-2-oxazolinyl)phenyl borate, [ToM]−, is prepared by reaction of 2-lithio-4,4-dimethyl-2-oxazolide and 0.3 equiv of dichlorophenylborane.
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Synthesis of New Chiral 2,2′-Bipyridyl-Type Ligands, Their Coordination to Molybdenum(0), Copper(II), and Palladium(II), and Application in Asymmetric Allylic Substitution, Allylic Oxidation, and CyclopropanationOrganometallics 2007, 26, 6586–6590 DOI: 10.1021/om700763v Extended Charge Decomposition Analysis and Its Application for the Investigation of Electronic Relaxation S Organometallics 2004 vol 23 21 p4970. I. Gorelsky and E. I. SolomonNotes A Surprising Solvent Effect on the Crystal Structure of an Anionic Lanthanide Sandwich Complex† Volker Lorenz, Anja Edelmann, Steffen Blaurock, Fritjof Freise, and Frank T. Edelmann*
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the nature of fluorine itself High electronegativity high hydration energy of fluoride anion Weak nucleophile in the presence of hydrogen bond donors Better nucleophile when hydrogen bond donors are meticulously exclude, but also a strong baseSelected Recent Publications. Journal Articles. Pearce, K.G.; Simenok, V.; Crossley, I.R. Dalton Trans., 2020, 49, in press "Phosphacycloalkyldiones: synthesis and.Coordination chemistry and reactivity of early transition metal complexes with the amine phenolate ligands Thesis for the Degree of “Doctor of Philosophy” By Stanislav Groysman Submitted to the Senate of Tel Aviv University September 2005